This is kinda silly. Did you mean the firsts that are in the record books all time in Super Bowl history? Like the 3 40+ yard FGs? If so, that makes sense. Otherwise you can say first time Jahri Evans ever made a block in a Super Bowl game, or Jonathan Casillas ever made a tackle on special teams, etc.
Brees was the first QB in history to go on a stretch of 18 of 19 completions. The only miss in that stretch was clocking the ball. So essentially he had 18 straight completions without a miss.
Saints first team ever to lose the last 3 games of the regular season and go on to win the Super Bowl.
Drew Brees technically completed 33 passes if you count the 2 point conversion, breaking the record held by Brady of 32.
On the Saints' final offensive touchdown drive, Brees completed seven passes in seven attempts to seven receivers. On the two-point conversion pass, he threw to an eighth receiver, Lance Moore. You know a coach means what he says about playing everyone on the roster and if you get open the ball's coming to you when on the biggest touchdown drive of the season eight receivers get their hands on Brees passes. That, my friend, is simply unreal.